Cover
Vol. 16 No. 2 (2025)

Published: December 15, 2025

Pages: 166-177

Research Paper

Performance of Geopolymer Concrete Based on Fly Ash Materials Exposed to Freezing and Thawing Cycle

Abstract

This paper deals with the behaviour of waste pozzolanic materials, such as fly ash (FA), ground granulated blast furnace slag (GGBS), rice husk ash (RHA) and burnt brick powder (BBP)-based geopolymer concrete (GPC) under a repeated freezing and thawing cycles. The study focuses on the impact of curing regimes (24 h, 48 h, 7 d and 28 d) and exposure to 25 and 35 F-T cycles on the mechanical and durability characteristics of GPC. In recent literature, analytical and numerical work has shown that micro-crack evolution and interconnected pores dictate the degradation of strength under cyclic freezing but limited experimental data are available for waste-based GPC systems. The concretes were mixed into specimen and cured at $60^{\circ}\text{C}$ in an oven for 24 h and tested according to standard F-T testing (ASTM C666). It was found that the loss in strength up to 35 cycles did not go beyond 18 %, and residual compressive strength was higher than 80% of original one, passing durability criteria according to ASTM C666 or EN 12390-9. The relationship between the strengths in compression and tensile strength, both of F-T aged and natural samples, were roughly linear ( $R^{2}\approx0.85).$ Deeper potassium hydroxide activation and the enrichment of RHA and BBP in the AC enhanced the porosity while decreasing the mass yields, as compared with previous results. These findings demonstrate the potential uses of waste-based geopolymer concretes as environmentally friendly and frost-resistant substitutes for ordinary Portland cement in construction in sub-arctic environment.

References

  1. P. Azarsa and R. Gupta, "Freeze-thaw performance characterization and leachability of potassium-based geopolymer concrete," J. Compos. Sci., vol. 4, no. 2, p. 45, 2020, doi: 10.3390/jcs4020045.
  2. W. M. Kriven et al., "Why geopolymers and alkali-activated materials are key components of a sustainable world: A perspective contribution," J. Am. Ceram. Soc., vol. 107, no. 8, pp. 5159-5177, 2024, doi: 10.1111/jace.19269.
  3. F. Li, D. Chen, Y. Lu, H. Zhang, and S. Li, "Influence of mixed fibers on fly ash-based geopolymer resistance against freeze-thaw cycles," J. Non-Cryst. Solids, vol. 584, p. 121517, 2022, doi: 10.1016/j.jnoncrysol.2022.121517.
  4. F. Li et al., "Flexural performance and damage of reinforced fly ash and slag-based geopolymer concrete after coupling effect of freeze-thaw cycles and sustained loading," Structures, vol. 64, p. 106537, 2024, doi: 10.1016/j.istruc.2024.106537.
  5. L. Tian, D. He, J. Zhao, and H. Wang, "Durability of geopolymers and geopolymer concretes: A review," Rev. Adv. Mater. Sci., vol. 60, no. 1, pp. 1-14, 2021, doi: 10.1515/rams-2021-0002.
  6. M. H. Shamsa, B. S. Al-Shathr, and T. S. Al-Attar, "Performance of geopolymer concrete exposed to freezing and thawing cycles," Eng. Technol. J., vol. 37, no. 3A, pp. 78-84, 2019, doi: 10.30684/etj.37.3A.1.
  7. A. F. H. Sherwani, K. H. Younis, and R. W. Arndt, "Fresh, mechanical, and durability behavior of fly ash-based self-compacted geopolymer concrete: Effect of slag content and various curing conditions," Polymers, vol. 14, no. 15, p. 3209, 2022, doi: 10.3390/polym14153209.
  8. A. F. Sherwani, R. A. Hawileh, J. A. Abdalla, and M. Z. Naser, "Freeze-thaw performance of sustainable self-compacting geopolymer concrete incorporating steel fibers and hybrid fly ash/slag blends," Polymers, vol. 14, no. 15, p. 3209, 2022, doi: 10.3390/polym14153209.
  9. R. Zhao, J. G. Sanjayan, and J. L. Wilson, "Durability of fly ash-based geopolymer concrete against freezing and thawing cycles," Constr. Build. Mater., vol. 211, pp. 528-539, 2019, doi: 10.1016/j.conbuildmat.2019.06.166.
  10. R. Zhao et al., "Freeze-thaw resistance of Class F fly ash-based geopolymer concrete," Constr. Build. Mater., vol. 222, pp. 474-483, 2019, doi: 10.1016/j.conbuildmat.2019.06.204.